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《化学科学与工程前沿(英文)》 2023年 第17卷 第10期 页码 1484-1502 doi: 10.1007/s11705-023-2331-y
关键词: polysulfone blend modification ultrafiltration membrane formation hydrodynamics poly(ethylene-co-vinyl alcohol) copolymer
Influence of accelerated curing on the compressive strength of polymer-modified concrete
Izhar AHMAD; Kashif Ali KHAN; Tahir AHMAD; Muhammad ALAM; Muhammad Tariq BASHIR
《结构与土木工程前沿(英文)》 2022年 第16卷 第5期 页码 589-599 doi: 10.1007/s11709-022-0789-1
关键词: compressive strength prediction polymer-modified concrete linear regression fit early age strength ethylene vinyl acetate
Insight of chemical environmental risk and its management from the vinyl chloride accident
《环境科学与工程前沿(英文)》 2023年 第17卷 第4期 doi: 10.1007/s11783-023-1652-x
关键词: Vinyl chloride Combustion Chemical safety management Environmental risk Emerging contaminants
Molecular diffusion in ternary poly(vinyl alcohol) solutions
《化学科学与工程前沿(英文)》 2022年 第16卷 第6期 页码 1003-1016 doi: 10.1007/s11705-021-2121-3
关键词: fluorescence correlation spectroscopy poly(vinyl alcohol) anomalous diffusion crowding effects dynamic light scattering binding effects rhodamine B
Catalysis of semihydrogenation of acetylene to ethylene: current trends, challenges, and outlook
《化学科学与工程前沿(英文)》 2022年 第16卷 第7期 页码 1031-1059 doi: 10.1007/s11705-021-2113-3
Electricity-driven ammonia oxidation and acetate production in microbial electrosynthesis systems
《环境科学与工程前沿(英文)》 2022年 第16卷 第4期 doi: 10.1007/s11783-021-1476-5
• MES was constructed for simultaneous ammonia removal and acetate production.
关键词: Biocathode Carbon dioxide Electrochemical oxidation Graphite anode Boron-doped diamond
《化学科学与工程前沿(英文)》 2023年 第17卷 第11期 页码 1765-1775 doi: 10.1007/s11705-023-2323-y
关键词: BiOBr nanosheet cellulose acetate silk fibroin photocatalytic degradation dye wastewater
Gas phase ethylene polymerization over SiO
Liuzhong LI, Aiyou HAO, Ruihua CHENG, Boping LIU
《化学科学与工程前沿(英文)》 2011年 第5卷 第1期 页码 89-95 doi: 10.1007/s11705-010-0558-x
关键词: UCC S-2 catalyst Al-alkyl co-catalyst gas-phase ethylene polymerization high density polyethylene
Progress on cleaner production of vinyl chloride monomers over non-mercury catalysts
Jinli ZHANG, Nan LIU, Wei LI, Bin DAI
《化学科学与工程前沿(英文)》 2011年 第5卷 第4期 页码 514-520 doi: 10.1007/s11705-011-1114-z
关键词: polyvinyl chloride vinyl chloride monomer acetylene hydrochlorination non-mercury catalysts green chemical process
Toughening of vinyl ester resins by two-dimensional MXene nanosheets
《化学科学与工程前沿(英文)》 页码 1651-1658 doi: 10.1007/s11705-022-2208-5
关键词: MXene nanosheets 2D material vinyl ester resin modification coupling agent
Methyl acetate–methanol mixture separation by extractive distillation: Economic aspects
Elena Graczová, Branislav Šulgan, Samuel Barabas, Pavol Steltenpohl
《化学科学与工程前沿(英文)》 2018年 第12卷 第4期 页码 670-682 doi: 10.1007/s11705-018-1769-9
Methyl acetate is considered low toxicity volatile solvent produced either as a by-product during methanol carbonylation or via acetic acid esterification with methanol. In both cases, pure methyl acetate has to be isolated from the reaction mixture. Simulation of methyl acetate separation from its mixture with methanol by extraction distillation was carried out in ASPEN+ software. In total three case studies were assumed using two different extraction solvents and two solvent regeneration strategies. In case A, novel extraction solvent 1-ethyl-3-methylimidazolium trifluoromethanesulfonate ionic liquid, was considered. Raw material separation was achieved in an extraction distillation column while the solvent regeneration was accomplished in a second distillation column in this case. In case study B, the same extraction solvent was used; however, its regeneration was carried out in a single-effect evaporator. Dimethyl sulfoxide was the second extraction solvent selected. Its use in methyl acetate-methanol separation is presented in case study C. As high purity of dimethyl sulfoxide was required for the methyl acetate-methanol azeotrope breaking, its regeneration was carried out in the second distillation column only. To simulate the ternary methyl acetate–methanol–extraction solvent mixtures separation, vapor–liquid equilibrium was predicted based on the NRTL equation. Further, unknown properties of the considered ionic liquid and variation of these properties with temperature were predicted and introduced into the ASPEN+ components properties database. Based on these data, optimum operation parameters of the respective separation equipment were established. In all case studies, the same condition had to be fulfilled, namely minimum methyl acetate content in the distillate from the extraction distillation column of 99.5mol-%. Results of simulations using the respective optimum operation parameters were employed in the economic evaluation of the three separation unit designs studied. It was found that the least energy-demanding design corresponds to the case study B in terms of both capital as well as operation expenses.
关键词: methyl acetate 1-ethyl-3-methylimidazolium trifluoromethanesulfonate extraction distillation dimethyl sulfoxide economic evaluation
聚乙烯吡咯烷酮/聚(乙烯-乙烯醇)共混膜的制备及其油水分离性能
白云翔,吴国梁,张春芳,顾瑾,孙余凭
《中国工程科学》 2014年 第16卷 第7期 页码 79-83
将聚乙烯吡咯烷酮(PVP)与聚(乙烯-乙烯醇)(EVAL)共混,采用浸没沉淀法制备了PVP/EVAL共混膜,并用于油水乳液分离过程。通过全反射红外光谱、扫描电子显微镜、拉伸试验、接触角测试等对膜的组成、结构形态、机械性能、亲水性进行了表征,并研究了PVP添加量对共混膜油水分离性能的影响。结果表明:添加PVP能较显著地改变EVAL膜的结构,且共混膜的机械强度和亲水性得到明显改善,当PVP添加量为10 wt%(PVP在铸膜液中的质量分数)时,其拉伸强度和断裂伸长率分别为纯EVAL膜的1.88 倍和1.34 倍。当PVP 添加量为4 wt%时,油水分离稳定通量为纯EVAL 膜的1.81 倍,截留率为92.2 %,比纯EVAL 膜略高。PVP 添加量为10 wt%的PVP/EVAL 共混膜清洗后通量恢复率由纯EVAL 膜的51 %增至77.98 %。
《化学科学与工程前沿(英文)》 2023年 第17卷 第9期 页码 1280-1288 doi: 10.1007/s11705-023-2301-4
关键词: ethylene glycol redistribution heat integration optimization parallel framework
Jie Gao, Zhikai Li, Mei Dong, Weibin Fan, Jianguo Wang
《化学科学与工程前沿(英文)》 2020年 第14卷 第5期 页码 847-856 doi: 10.1007/s11705-019-1848-6
Catalytic oxidation of carbon monoxide, toluene, and ethyl acetate over the
Zhidan Fu, Lisha Liu, Yong Song, Qing Ye, Shuiyuan Cheng, Tianfang Kang, Hongxing Dai
《化学科学与工程前沿(英文)》 2017年 第11卷 第2期 页码 185-196 doi: 10.1007/s11705-017-1631-5
关键词: cryptomelane-type manganese oxide octahedral molecular sieve oxygen mobility reducibility carbon monoxide oxidation volatile organic compound combustion
标题 作者 时间 类型 操作
Uncovering the effect of poly(ethylene-co-vinyl alcohol) molecular weight and vinyl alcohol content on
期刊论文
Influence of accelerated curing on the compressive strength of polymer-modified concrete
Izhar AHMAD; Kashif Ali KHAN; Tahir AHMAD; Muhammad ALAM; Muhammad Tariq BASHIR
期刊论文
Catalysis of semihydrogenation of acetylene to ethylene: current trends, challenges, and outlook
期刊论文
Electricity-driven ammonia oxidation and acetate production in microbial electrosynthesis systems
期刊论文
Durable and recyclable BiOBr/silk fibroin-cellulose acetate composite film for efficient photodegradation
期刊论文
Progress on cleaner production of vinyl chloride monomers over non-mercury catalysts
Jinli ZHANG, Nan LIU, Wei LI, Bin DAI
期刊论文
Methyl acetate–methanol mixture separation by extractive distillation: Economic aspects
Elena Graczová, Branislav Šulgan, Samuel Barabas, Pavol Steltenpohl
期刊论文
Optimization and simultaneous heat integration design of a coal-based ethylene glycol refining process
期刊论文
Thermodynamic analysis of ethanol synthesis from hydration of ethylene coupled with a sequential reaction
Jie Gao, Zhikai Li, Mei Dong, Weibin Fan, Jianguo Wang
期刊论文